A vessel of volume 5 liters was filled with 2 moles of hydrogen gas (a), then a further
1 mole of chlorine gas (b), and then the mixture was sparked leading to the formation of 1 mole of HCI (g) (c). What are the partial pressure of the components
and the total pressure of the system at the final stage. The temperature being 25°C throughout.
According to the reaction
H2 + Cl2 --> 2HCl,
if 1 mole of HCl was formed, 0.5 moles of each H2 and Cl2 have actually reacted. Therefore, the final amounts of each gas are:
H2: 2 - 0.5 = 1.5 mol
Cl2: 1 - 0.5 = 0.5 mol
HCl: 1 mol
Now, partial pressures can be determined:
According to the Dalton's law,
Answer: H2 - 7.34 atm; Cl2 - 2.45 atm; HCl - 4.89 atm; total - 14.7 atm
Comments