Question #29216

A 1.00kg block of copper at 20degreesC is dropped into a large vessel of liquid nitrogen a -196degressC. How many kilograms of nitrogen boil away by the time the coper reaches -196degressC? The specific heat capacity of coppe is 0.385kJ/gdegressC and the heat of vaporization of nitrogen is 5.57 kJ/mol.
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Expert's answer

2013-04-29T08:44:49-0400

Question #29216, Physics, Other

A 1.00kg block of copper at 20 degrees C is dropped into a large vessel of liquid nitrogen at -196 degrees C. How many kilograms of nitrogen boil away by the time the copper reaches -196 degrees C? The specific heat capacity of copper is 0.385kJ/g degrees C and the heat of vaporization of nitrogen is 5.57 kJ/mol.

Solution.

Find the heat quantity which need take from copper:


Q=m(Cu)C(Cu)(T1T2)=1.000.385(20(196))=83.16 kJ;Q = m(Cu) \cdot C(Cu) \cdot (T_1 - T_2) = 1.00 \cdot 0.385 \cdot (20 - (-196)) = 83.16 \text{ kJ};


where m(Cu)m(Cu) – mass of the copper block, kg;

C(Cu)=0.385 kJ/(kg*C)C(Cu) = 0.385 \text{ kJ/(kg*C)} is the specific heat capacity of copper;

This heat is equal to the heat of nitrogen vaporization:


Q=λ(N2)m(N2)M(N2);Q = \lambda(N_2) \cdot \frac{m(N_2)}{M(N_2)};


where λ(N2)=5.57 kJ/mol\lambda(N_2) = 5.57 \text{ kJ/mol}, is the heat of one mole nitrogen vaporization.

m(N2)m(N_2) – nitrogen mass, kg;

M(N2)=0.028 kg/molM(N_2) = 0.028 \text{ kg/mol} – nitrogen molar mass;

Find the mass of nitrogen:


m(N2)=QM(N2)λ(N2)=83.160.0285.57=0.418 kg;m(N_2) = \frac{Q \cdot M(N_2)}{\lambda(N_2)} = \frac{83.16 \cdot 0.028}{5.57} = 0.418 \text{ kg};


Answer: the mass of nitrogen is 0.418 kg.

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