Fe(aq)2++2e−→Fe(s) Eθ=−0.44
If the cell has Fe rod in FeSO4 at concentration of 0.25M and Cu rod in copper solution of 0.45M
Then E.M.F can be calculated as follows;
Ecellθ=ECu2+/Cu0−EFe2+/Fe0=0.34−(−0.44)
=0.78
Ecellθ=0.78+20.0592log0.450.25
=0.77V
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