Question #254015
Show that at high pressures, the compressibility factor z is greater than 1 and at low pressures, z is less than unity.
1
Expert's answer
2021-10-21T02:09:35-0400

The compressibility of a real gas is given by,

Z=1+PBRTaVRTZ= 1+\frac{PB}{RT}-\frac{a}{VRT}

At high T, value of a/VRT decreases

Also at high T, P is high due to which PBRT\frac{PB}{RT} increases.

The increase in the second compensates the decrease in the first due to which net value of Z>1 .


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