The following kinetic data (π£0 is the initial rate) were obtained for the reaction: 2πΌπΆπ(π) + π»2(π) β πΌ2(π) + 2π»πΆπ(π) Experiment [πΌπΆπ]0 (ππππ. ππβ3 ) [π»2]0 (ππππ. ππβ3 ) π£0 (ππππ. ππβ3 ) 1 1.5 1.5 3.7 x 10-7 2 3.0 1.5 7.4 x 10-7 3 3.0 4.5 22 x 10-7 4 4.7 2.7 ? (a) Write the rate law for the reaction [2] (b) From the data, determine the value of the rate constant [2]
Rate law is expression where we defined rate of reaction with a tive mass of reactant with some power .( order )
Order is experimental may be zero , fraction positive and negative .
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