Answer to Question #146673 in Physical Chemistry for Sanaa

Question

1. Calculate the pH (give your answers to 2.d.p) of the following strong bases at 298 K.
(a) 0.100 mol dm–3 NaOH
(b) 0.100 mol dm–3 Ca(OH)2
(c) 0.0500 mol dm–3 KOH

Answer 1

Solution.

i) [OH- ] = 0.100 moldm^-3

 [H+] = K_w/[OH- ] = 10^-14/0.100 = 10^-13  pH = -log[10^-13] = 13.00

(ii) [OH- ] = 0.200 moldm^-3

 [H+] = K_w/[OH- ] = 10^-14/0.100 = 5 x 10^-14  pH = -log[5 x 10^-14] = 13.30

iii) [OH- ] = 0.050 moldm^-3

[H+] = K_w/[OH- ] = 10^-14/0.100 = 2 x10^-13  pH = -log[2 x 10^-13] = 12.69(Ans.)