Use Ideal gas relation "V1\/T1=V2\/T2" at constant pressure and number of moles
given
initial temperature T1 = 250 K
final temperature T2 = 500 K
initial volume V1 = ?
final volume V2 = 12.0 L
Thus V1 = V2* T1/T2
plug in given numbers
V1 = 12.0 L * 250 K/500 K = 6.00 L
The gas law which explains the relation between volume and temperature is Charles's Law
Answer
original volume = 6.00 L
Law explained here is = Charles's law
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