It is assumed that 1 teaspoon =5 ml
1/8 of teaspoon = (1/8)*5=0.625 ml
As the density of water is 1 g/cc
Hence mass of 0.625 ml is equal to 0.625 grams
Molar mass of water = 18 g
Moles of water in 0.625 g of water = 0.625/18 = 0.0347
Number of molecules = 0.0347*NA = 0.0347*6.022*1023 = 0.2*1023
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