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Alkynes are less reactive than alkenes towards electrophilic reagents. Explain.
Reaction of 1,3- butadiene to maleic acid gives cis product while fumaric acid
gives trans product. Explain.
In case of addition reaction of HBr to propenenitrile, the secondary
carbocation is less stable than the primary carbocation while in chloroethene
secondary carbocation is more stable than primary carbocation. Explain.
In SN2 mechanism inversion of configuration takes place. Explain.
Arrange the following carbocations in the order of increasing stability.
i) (C6H5)3C
+
, C6H5 = C H2 , (C6H5)2CH, CH2 = CH-CH2
Isotopes have been used to study the reaction path and mechanism. Explain.
The nucleophilicity is different from the basicity. Explain.
NO2 is a better electrophile as compared to NH4. Explain.
A tertiary amine is more basic than a primary amine. Explain.
Consider compound A=2 chloro 2 methyl butane,B=2 chloro butane, C = chloro propane,(i) which of the compound will readily undergo dehydrochlorination (ii) what informs your answer?
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