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An organometallic cyclic compound (E; C6H11MgBr) was synthesized by one of my PhDscholars followed by magnesium in dry ether which was further react with butanal to yielda macromolecule alcoholic compound (F) after mild acidification. Prolonged treatment of
F with an equivalent amount of hydrogen bromide to 1-bromo-1-butylcycloheptane (G).
Write the structures of (E) and (F), and explain how (G) is obtained from (F).

A current is forced through a cell consisting of two platinum electrodes in which each is immersed in a solution of CuSO4 and H2SO4. During the process copper is deposited at the cathode while evolution of oxygen occurs at the anode. The standard potential (Eo) for the reaction occurring at cathode and anode are 0.34V and 1.23V respectively.
(i) Write down the chemical equation for both the cathodic and anodic reactions.
(ii) What is the overall reaction and determine the theoretical decomposition potential?
(iii) Estimate the potential required for the operation of the cell if an additional 0.5V is applied to overcome the resistance of the cell to the current.
We pour a 10l mixture of He, CO2 and CH4 in a container with NaOH. The volume of the gas that comes out is 7,24l. This gas that comes out reacts with 0.4 mol of Cl in presence of UV rays to give CCl4. Write the chemical reactions and determine the percentage of each ingredient in the 10l mixture.
a chemical compound has 54.55% carbon and 9.09% hydrogen. Determine the chemical formula if its molar mass is 70g / mol
How do you show the mechanism of an anime attaching to a dihydropyran derivatised ring when the conditions are acidic ?

Calculate the reaction free energy of

H2(g) + I2(g) 2HI(g)

when the concentrations are 0.006 mol L-1 (H2), 0.03 mol L-1 (I2), and 1.27 mol L-1 (HI), and the temperature is 700K. For this reaction Kc = 54 at 700 K.


+52,100 kJ mol-1

+52 kJ mol-1

-29.8 kJ mol-1

+29.8 kJ mol-1


What are the composition of organic compounds?


What terms are generated by the configuration (e1g)2 (e2u)2 in D6h symmetry?
Suppose that a 5.0£10¡5 M solution of a compound had a %T equal to 70.80 when measured in a
cuvette with a 1.0 cm path length. Find themolar extinction coefficient of this compound.
What is the relationship between absorbance and %T?
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