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Compare the mechanisms for the following substitution and addition reactions of benzene:

o the Friedel-Crafts reaction 

o the sulfonation of benzene

o the chlorination of benzene 

o the hydrogenation benzene

You will need to illustrate and explain the reaction mechanism for each one, as well as the similarities and differences that exist between them.



hydrolysis  of  3 -fluorobutyl-2-methylpentanoate 


Propose on solution mechanism for the solution of 3-bromo -2,3-dimethyl pentane in ethanol



Determine the change in volume that takes place when 2.36 L sample of N2 (g) is heated from 250.0 k to 464.4 k


What is the IUPAC name of the following alkane?


CH3 CH3

| |

CH3 – CH – CH2 – C – CH2 – CH – CH3

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CH3 CH2

|

CH3


  1. Calculate the molar solubility of Ag ion in AgCl? (Ksp = 1.6x10-10)

AgCl (s) ↔ Ag+ (aq) + Cl- (aq)

2.Ka for acetic acid is 1.75x10-5. Find Kb for acetate ion at 25oC. (Kw= 1.0 x 10-14)


What volume of solution is needed to dissolve 35.6 grams of KOH into a 71% solution?



For liquids are described in the table below. Use the second column of the table to explain the order of their freezing points and a third column to explain the order of their boiling points.


6.6 g of sucrose (C12H22O11) dissolved in 150.ml of water


6.6 g of potassium nitrate (KNO3) dissolved in 150.ml of water


6.6 g of sodium chloride (NaCl) dissolved in 150.ml of water


150.ml of pure water


A certain substance X condenses at a temperature of 147.2 °C. But if a 800. g sample of X is prepared with 77.9 g of urea ((NH2)2Co) dissolved in it, the

sample is found to have a condensation point of 150.7 °C instead. Calculate the molal boiling point elevation constant Kb of X.

Be sure your answer has the correct number of significant digits 



Some nuclear power plants use seawater as a coolant .choosing the correct type of piping to carry seawater is critical because seawater contains trace amounts of dissolved silver and gold ions. Is copper piping a suitable choice?



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