Answer to Question #97262 in Organic Chemistry for Anthony

Question #97262
A 0.3259g of (KPH) required 20.15ml of NaOH for neutralization. Calculate the molarity of NaOH
1
Expert's answer
2019-10-25T05:30:40-0400

Answer on Question #97262 – Chemistry – Organic Chemistry


Task:

A 0.3259g of (KPH) required 20.15ml of NaOH for neutralization. Calculate the molarity of NaOH.


Solution:

"KHP" - potassium hydrogen phthalate (KHC8H4O4, Molar mass = 204.2 g/mol).

KHP has one acidic hydrogen atom, and reacts with NaOH on a 1:1 stoichiometric basis:

KHC8H4O4 + NaOH = NaKC8H4O4 + H2O.

Then,

n(KHP) = n(NaOH);

m(KHP) / M(KHP) = Cm(NaOH)*V(NaOH);

Cm(NaOH) = m(KHP) / (M(KHP*V(NaOH);

Cm(NaOH) = 0.3259 / (204.2 * 0.02015) = 0.0792 (mol/L).


Answer: Cm(NaOH) = 0.0792 mol/L.

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