Phenol and amphetamine have different functional groups thus may be distinguished by IR spectra.
Phenol has absorption at around 1230-1240 cm-1 that is characteristic IR band of C-O bond. O-H absorption band is broad at 3200-3300 cm-1.
Amphetamine is a primary amine, having medium strength absorption bands of amino group at 3450 cm-1 () and 1600 cm-1. Medium-strong line of amphetamine at around 1000-1100 cm-1 (C-N) helps to distinguish it from phenol.
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