Question #74938

Reaction between potassium cyanide and 1 chloropropane

Expert's answer

Answer:

If a halogenoalkane is heated under reflux with a solution of sodium or potassium cyanide in ethanol, the halogen is replaced by a -CN group and a nitrile is produced. Heating under reflux means heating with a condenser placed vertically in the flask to prevent loss of volatile substances from the mixture.


CH3CH2CH2Br+KCNCH3CH2CH2CN+KBr\mathrm{CH_3CH_2CH_2Br} + \mathrm{KCN} \longrightarrow \mathrm{CH_3CH_2CH_2CN} + \mathrm{KBr}


The bromine (or other halogen) in the halogenoalkane is simply replaced by a -CN group - hence a substitution reaction. In this example, butanenitrile is formed


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