Question #43599

If 0.250 mol of red phosphorus reacts with 0.375 mol of yellow sulfur, what is the empirical formula of the product?

Expert's answer

Answer on Question #43599 - Chemistry - Organic Chemistry

Question:

If 0.250 mol of red phosphorus reacts with 0.375 mol of yellow sulfur, what is the empirical formula of the product?

Answer:

Generally, when phosphorus reacts with sulfur mixture of phosphorus sulfides (PxSy)(P_{x}S_{y}) is formed. The molar ratio


nPnS=0.2500.375=23\frac{n_{P}}{n_{S}} = \frac{0.250}{0.375} = \frac{2}{3}


So, the empirical formula of the product is P2S3P_{2}S_{3}.

By the way, phosphorus sulfide always includes 4 P atoms. So the actual formula of the product is P4S6P_{4}S_{6}.

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