Question #37993

anthranilic acid at ph = 0 exists as ? and migrates towad which electrode during electrolysis??
1

Expert's answer

2014-01-09T08:10:31-0500

Answer on Question#37993-Chemistry-Organic Chemistry

Question

Anthranilic acid at pH=0\mathsf{pH} = 0 exists as ...? and migrates toward which electrode during electrolysis?

Answer

The pH=0\mathsf{pH} = 0 means that the solution is strongly acidic, i.e. there is abundance of protons in it. Anthranilic acid (or 2-aminobenzoic acid) involves an amino group in its structure. In strongly acidic medium amino group is protonated:



Thus, at pH=0\mathsf{pH} = 0 anthranilic acid exists as 2-carboxyanilinium ion.

Since the ion is positively charged, it migrates to the negatively charged electrode (cathode) during electrolysis.

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