Question #32103

when ethyle bromide and methyle bromide is subjected to wurtz reaction the products are ?

Expert's answer

when ethyle bromide and methyle bromide is subjected to wurtz reaction the products are ?

Solution:

Wurtz reaction is unspecific, so if there are several active compounds in mixture, they combine in all possible ways:


C2H5Br+NaC2H5+NaBr\mathrm{C_2H_5Br} + \mathrm{Na} \rightarrow \mathrm{C_2H_5} \bullet + \mathrm{NaBr}CH3Br+NaCH3+NaBr\mathrm{CH_3Br} + \mathrm{Na} \rightarrow \mathrm{CH_3} \bullet + \mathrm{NaBr}2C2H5C2H5C2H52\mathrm{C_2H_5} \bullet \rightarrow \mathrm{C_2H_5} \cdot \mathrm{C_2H_5}C2H5+CH3C2H5CH3\mathrm{C_2H_5} \bullet + \mathrm{CH_3} \bullet \rightarrow \mathrm{C_2H_5} \cdot \mathrm{CH_3}2CH3CH3CH32\mathrm{CH_3} \bullet \rightarrow \mathrm{CH_3} \cdot \mathrm{CH_3}C2H5Br+CH3Br+NaC2H5C2H5+C2H5CH3+CH3CH3+NaBr\mathrm{C_2H_5Br} + \mathrm{CH_3Br} + \mathrm{Na} \rightarrow \mathrm{C_2H_5} \cdot \mathrm{C_2H_5} + \mathrm{C_2H_5} \cdot \mathrm{CH_3} + \mathrm{CH_3} \cdot \mathrm{CH_3} + \mathrm{NaBr}


So in this mixture as products we have ethane (CH3CH3)(\mathrm{CH_3} \cdot \mathrm{CH_3}), propane (C2H5CH3)(\mathrm{C_2H_5} \cdot \mathrm{CH_3}) and butane (C2H5C2H5)(\mathrm{C_2H_5} \cdot \mathrm{C_2H_5}).

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