Because Calcium (Ca) has an oxidation number of +2.
Calcium needs two electrons to be stable but a Chlorine atom can only give out one electron.
Therefore, for Calcium to be stable, 2 chlorine atoms will give an electron each to Calcium
In order words, balanced and stable Calcium chloride has one atom of Ca and 2 atoms of Cl, forming 1Ca + 2Cl -- CaCl"_2"
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