Answer to Question #126528 in Organic Chemistry for Kamli Ramli

Question

Write isolation of functional group in polypropylene with reaction. Give full reaction.

Answer 1

Polypropylene, a synthetic resin built up by the polymerization of propylene. One of the important family of polyolefin resins, polypropylene is molded or extruded into many plastic products in which toughness, flexibility, light weight, and heat resistance are required. It is also spun into fibres for employment in industrial and household textiles. Propylene can also be polymerized with ethylene to produce an elastic ethylene-propylene copolymer.

Propylene is a gaseous compound obtained by the thermal cracking of ethane, propane, butane, and the naphtha fraction of petroleum. Like ethylene, it belongs to the “lower olefins,” a class of hydrocarbons whose molecules contain a single pair of carbon atoms linked by a double bond. The chemical structure of the propylene molecule is CH₂=CHCH₃. Under the action of polymerization catalysts, however, the double bond can be broken and thousands of propylene molecules linked together to form a chainlike polymer (a large, multiple-unit molecule). In such a molecule each propylene repeating unit has the following structure:

.

Essentially, the molecule consists of a backbone of carbon atoms with attached hydrogen atoms; attached to every other carbon atom is a pendant methyl group (CH₃). The methyl groups can adopt a number of tacticities, or spatial arrangements in relation to the carbon chain, but in practice only the isotactic form (i.e., with the methyl groups arranged along the same side of the chain) is marketed in significant quantities.

Isotactic polypropylene is produced at low temperatures and pressures, using Ziegler-Natta catalysts. The polymer shares some of the properties of polyethylene, but it is stronger, stiffer, and harder, and it softens at higher temperatures. (Its melting point is approximately 170 °C [340 °F].) It is slightly more prone to oxidation than polyethylene unless appropriate stabilizers and antioxidants are added. Polypropylene is blow-molded into bottles for foods, shampoos, and other household liquids. It is also injection-molded into many products, including appliance housings, dishwasher-safe food containers, toys, automobile battery casings, and outdoor furniture.

When a thin section of molded polypropylene is flexed repeatedly, a molecular structure is formed that is capable of withstanding much additional flexing without failing. This fatigue resistance has led to the design of polypropylene boxes and other containers with “self-hinged” covers.

A large proportion of polypropylene production is melt-spun into fibres. Polypropylene fibre is a major factor in home furnishings such as upholstery and indoor-outdoor carpets. Numerous industrial end uses exist as well, including rope and cordage, disposable nonwoven fabrics for diapers and medical applications, and nonwoven fabrics for ground stabilization and reinforcement in construction and road paving. These applications take advantage of the toughness, resilience, water resistance, and chemical inertness of the polymer. However, because of its very low moisture absorption, limited ability to take a dye, and low softening point (an important factor in ironing and pressing), polypropylene is not an important apparel fibre.