Substituted cyclobutadiene derivatives with bulky alkyl groups are easier to isolate instead of
unsubstituted cyclobutadiene. Do you find any reason behind?
1
Expert's answer
2020-06-05T05:13:12-0400
Unsubstituted cyclobutadiene is prone to dimerization, so it is very difficult to isolate it in its pure form. The presence of bulk substituents, such as tert-butyl, prevents dimerization due to steric complications.
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