Al2(SO4)3 + 3BaCl2 = 3BaSO4 + 2AlCl3
C(BaCl2) = 0.2/0.5 = 0.4 M
n(SO42-) = 3*3/1000 = 0.009 mol
n(BaCl2) = 0.009 mol
V(BaCl2) = 0.009/0.4 = 0.0225 L = 22.5 mL
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