You have to put coefficient 2 at the water formula:
Ba(OH)2(aq)+H2SO4(aq)→BaSO4(s)+2H2O(l)Ba(OH)_2(aq)+H_2SO_4(aq) \rightarrow BaSO_4(s)+2H_2O(l)Ba(OH)2(aq)+H2SO4(aq)→BaSO4(s)+2H2O(l)
It is double displacement reaction (AB + CD = AD + BC).
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