Question #78751

For a first order reaction, it takes 37 min for a reactant to decrease to 50% of its initial value. What is the rate constant for the reaction?
1

Expert's answer

2018-07-02T07:16:28-0400

Question #78751, Chemistry / General Chemistry

For a first order reaction, it takes 37 min for a reactant to decrease to 50% of its initial value.

What is the rate constant for the reaction?

Solution:

τ1/2=ln2k=0.693k\tau_{1/2} = \frac{\ln 2}{k} = \frac{0.693}{k}k=0.693τ1/2=0.69337603.1104 [c1]k = \frac{0.693}{\tau_{1/2}} = \frac{0.693}{37*60} \approx 3.1 * 10^{-4} \ [c^{-1}]


Answer: 3.1104c13.1 * 10^{-4} c^{-1}

Source: https://opentextbc.ca/chemistry/chapter/12-4-integrated-rate-laws/

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