Question #76761

1.Rank the lead halide salts in order of their solubility in water?
2.Which is more soluble in water, NaIO3 or CSIO3?
3. Rank the group 2 Carbonates in order of thermal stability ?

Expert's answer

Answer on Question #76761 – Chemistry – General Chemistry

You gets TWO isolates. NaSO4\mathrm{NaSO_4}, and CdO2\mathrm{CdO_2}, . I suspect that the caesium salt would be more insoluble. Because, the caesium cation is larger than the sodium one, and thus there is probably a better size match between the caesium and iodate ion-pair, and thus decreased solubility.

For the least halide series:

Kac:PNC(21.70+103)\mathrm{K_{ac}:PNC(21.70 + 10^{-3})}

PHBr2(6.60+104);PH2(0.80+104)\mathrm{PHBr_2(6.60 + 10^{-4})};\mathrm{PH_2(0.80 + 10^{-4})} the which gives.

PNCI2\mathrm{PNCI_2} is PHBr2=PHI2\mathrm{PHBr_2 = PHI_2}

order of decreasing solubility:

Size matching between anion, and cation, probably again plays a part here.

As for the alkaline earth carbonates, you are probably going to have to consult your test. A size mismatch again probably lowers the temperature of decomposition, but you need data to argue your position.

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