Question

explain the tetrahedral structure of chlorine oxide with a bond angle of more than109 28'.

Answer 1

Question #75803, Chemistry / Inorganic Chemistry / Completed

Explain the tetrahedral structure of chlorine oxide with a bond angle of more than 109°28'

Answer:

The structure of dichlorine monoxide is similar to that of water and hypochlorous acid, with the molecule adopting a bent molecular geometry due to the lone pairs on the oxygen. The bond angle is slightly larger than normal, likely due to steric repulsion between the bulky chlorine atoms. In the solid state, it crystallises in the tetrahedral space group I41/amd, making it isostructural to the high pressure form of water*

* https://en.wikipedia.org/wiki/Dichlorine_monoxide

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