Question #57535

How can we determine Chromium ion in a sample other than borax bead test or cobalt nitrate test?

Expert's answer

Answer on Question #57535 – Chemistry – Inorganic chemistry

Question: How can we determine Chromium ion in a sample other than borax bead test or cobalt nitrate test?

Answer:

1) Cr3++3OHCr(OH)3\mathrm{Cr}^{3+} + 3\mathrm{OH}^{-} \rightarrow \mathrm{Cr}(\mathrm{OH})_{3}\downarrow (green precipitate)

Cr(OH)3+3OH[Cr(OH)6]3\mathrm{Cr(OH)}_3 + 3\mathrm{OH}^- \rightarrow [\mathrm{Cr(OH)}_6]^{3-} (green solution)

2) 2Cr3++3OCl+10OH3Cl+5H2O+2CrO422 \mathrm{Cr}^{3+} + 3 \mathrm{OCl}^{-} + 10 \mathrm{OH}^{-} \rightarrow 3 \mathrm{Cl}^{-} + 5 \mathrm{H}_{2} \mathrm{O} + 2 \mathrm{CrO}_{4}^{2-} (yellow solution)

Ba2++CrO42BaCrO4\mathrm{Ba}^{2+} + \mathrm{CrO}_{4}^{2-} \rightarrow \mathrm{BaCrO}_{4}\downarrow (yellow precipitate)

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