Question #49542

Define secular equation for valency

Expert's answer

Answer on Question #49542, Chemistry, Other

**Task:**

Define secular equation for valency

**Answer:**

The valence bound wave function can be written as:


ψ=kCkΦk\psi = \sum_{k} C_{k} \Phi_{k}


The structure coefficient Ck can be found by solving the secular equation:


HC=ESCHC = ESC


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