Question #48949

Calculate the frequency of the radiation required to eject photoelectrons to a velocity of 9 X105 MS-1 from sodium metal surface, having a threshold frequency of 4.61 x 1014 Hz (mass of photoelectron = 9.109 x 10 -31 kg).

Expert's answer

Answer on Question #48949 – Chemistry – Inorganic Chemistry

Question:

Calculate the frequency of the radiation required to eject photoelectrons to a velocity of 9×105MS19 \times 10^{5} \, \text{MS}^{-1} from sodium metal surface, having a threshold frequency of 4.61×1014Hz4.61 \times 10^{14} \, \text{Hz} (mass of photoelectron = 9.109×1031kg9.109 \times 10^{-31} \, \text{kg})

Solution:

According to Einstein’s equation energy of photon (irradiation energy) is given by


hν=m×ν2/2+Ah\nu = m \times \nu^{2}/2 + A


where ν\nu – the irradiation frequency, ν\nu – the velocity of photo electrons, AA – the work function and h=6.62606957×1034J sh = 6.62606957 \times 10^{-34} \, \text{J s}.

The work function can be calculated using the threshold frequency (v0)(v_0) when V=0V = 0:


A=hν0A = h\nu_0


Thus, v=(m×ν2/2+hν0)/hv = (m \times \nu^{2}/2 + h\nu_0)/h

v=(9.109×1031kg×40.5×1010m2/s2)/(6.62606957×1034J s)+4.61×1014Hz==5.56762×1014Hz+4.61×1014Hz=10.17762Hz\begin{aligned} v &= (9.109 \times 10^{-31} \, \text{kg} \times 40.5 \times 10^{10} \, \text{m}^2/\text{s}^2)/(6.62606957 \times 10^{-34} \, \text{J s}) + 4.61 \times 10^{14} \, \text{Hz} = \\ &= 5.56762 \times 10^{14} \, \text{Hz} + 4.61 \times 10^{14} \, \text{Hz} = 10.17762 \, \text{Hz} \end{aligned}


Answer: 10.17762 Hz

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