Question #48946

Calculate the magnetic moment in 1113 units for a paramagnetic substance having three unpaired electrons.

Expert's answer

Answer on Question #48946 – Chemistry – Inorganic Chemistry

Question:

Calculate the magnetic moment in 1113 units for a paramagnetic substance having three unpaired electrons.

Answer:

The effective magnetic moment caused by spin values for paramagnetic compound is defined:

μ=g×[S(S+1)]1/2\mu = g \times [S(S + 1)]^{1/2}, where SS – a total spin for the unit, gg – the constant being of 2.0023

The total spin equals:

S=n×1/2=3×1/2=3/2S = n \times 1/2 = 3 \times 1/2 = 3/2, where nn – the number of unpaired electrons.

Thus, for 1 unit, μ=2.0023×[3/2(3/2+1)]1/2=3.87μB\mu = 2.0023 \times [3/2(3/2 + 1)]^{1/2} = 3.87 \mu_{B}, where μB=9.274×1024J T1\mu_{B} = 9.274 \times 10^{-24} \, \text{J T}^{-1}

The total magnetic moment can be found from the equation:

M=m×μM = m \times \mu, where mm – the number of units.

So, M=1113×3.87μB=4307.31μB=39946×1024J T14×1020J T1M = 1113 \times 3.87 \mu_{B} = 4307.31 \mu_{B} = 39946 \times 10^{-24} \, \text{J T}^{-1} \approx 4 \times 10^{-20} \, \text{J T}^{-1}

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