Question #48221, Chemistry, Inorganic Chemistry
How many charge clouds are there around a central atom in molecules that have the following geometry?
1. tetrahedral
2. octahedral
3. bent
4. linear
5. square pyramidal
6. Trigonal pyramidal
Answer:
The charge of the electron cloud depends on the number of valence electrons. This amount depends on the type of hybridization of the central atom.
1. Tetrahedral (CH₄) n=4
2. Octahedral (SF₆) n=6
3. Bent (H₂O) n=2
4. Linear (CO₂) n=2
5. Square pyramidal (BrF₅) n=5
6. Trigonal pyramidal (NH₃) n=3
Qₑ=1.6·10⁻¹⁹ C
Q_cloud = Qₑ·Z + Qₑ·n·x
Z- atomic number; n- number of bonds; x- multiplicity of communication
For example:
N₂ n=1 x=3 N≡N
Q_cloud=7·1.6·10⁻¹⁹+3·1·1.6·10⁻¹⁹=1.6·10⁻¹⁸
BrF₅ n=5 x=1
Q_cloud=35·1.6·10⁻¹⁹+5·1·1.6·10⁻¹⁹=6.4·10⁻¹⁸
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