Question #43447

What is the pH of a 0.025M solution of hydrochloric acid?

1. 16.0
2. 3.68
3. 0.16
4. 1.60
5. 0.025

How do I work this out?

Expert's answer

Answer on Question #43447 - Chemistry – Inorganic Chemistry

Question:

What is the pH of a 0.025M solution of hydrochloric acid?

1. 16.0

2. 3.68

3. 0.16

4. 1.60

5. 0.025

How do I work this out?

Answer:

1. pH equals:


pH=lg[H+]\mathrm{pH} = -\lg \left[ \mathrm{H}^{+} \right]

[H+]\left[\mathrm{H}^{+}\right] – Molar concentration of H+\mathrm{H}^{+} ions.

Hydrochloric acid is a strong acid and it fully dissociates in water:


HCl(aq)H(aq)++Cl(aq)\mathrm{HCl}_{\mathrm{(aq)}} \leftrightarrow \mathrm{H}^{+}_{\mathrm{(aq)}} + \mathrm{Cl}^{-}_{\mathrm{(aq)}}


We see that the concentration of H+\mathrm{H}^{+} ions is equal to the concentration of HCl. Therefore H+\mathrm{H}^{+} ion concentration is:


[H+]=C(HCl)=0.025M=0.025mol/L\left[ \mathrm{H}^{+} \right] = \mathrm{C}(\mathrm{HCl}) = 0.025 \mathrm{M} = 0.025 \mathrm{mol/L}


So, pH value of 0.025 M HCl is:


pH=lg(0.025)=1.60\mathrm{pH} = -\lg (0.025) = 1.60

Answer: (4): $\mathrm{pH} = 1.60$

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