Question #36285

is negitive ph value possiable

Expert's answer

is negative ph value possible?

Solution

The constant of dissociation of water is 110141\cdot 10^{-14}

As far as the ph=log[H]+\mathsf{ph} = -\log [\mathsf{H}]^{+} and pOH=log[OH]\mathsf{pOH} = -\log [\mathsf{OH}]^{-}

[OH][H]+=1014;log[H]+log[OH]=log(1014);pOH+pH=14;[ \mathrm {O H} ] ^ {-} \cdot [ \mathrm {H} ] ^ {+} = 1 0 ^ {- 1 4}; - \log [ \mathrm {H} ] ^ {+} - \log [ \mathrm {O H} ] ^ {-} = - \log (1 0 ^ {- 1 4}); \mathrm {p O H} + \mathrm {p H} = 1 4;


So, if the pOH=15\mathsf{pOH} = 15 ([OH]=1015mol/l[\mathrm{OH}]^{-} = 10^{-15}\mathrm{mol / l}), pH=1\mathsf{pH} = -1

Any acid that yields a concentration of hydrogen ions with a molarity greater than 1 will be calculated to have a negative pH. For example, the pH of 12M HCl is calculated to be log(12)=1.08-\log(12) = -1.08.

**Answer:** the pH can be negative.

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