is negative ph value possible?
Solution
The constant of dissociation of water is 1⋅10−14
As far as the ph=−log[H]+ and pOH=−log[OH]−
[OH]−⋅[H]+=10−14;−log[H]+−log[OH]−=−log(10−14);pOH+pH=14;
So, if the pOH=15 ([OH]−=10−15mol/l), pH=−1
Any acid that yields a concentration of hydrogen ions with a molarity greater than 1 will be calculated to have a negative pH. For example, the pH of 12M HCl is calculated to be −log(12)=−1.08.
**Answer:** the pH can be negative.