Question #31839

crystals of a substance changed their colour on heating in a closed vessel but regained after sometimes,when they allowed to cool down.
name the substance

Expert's answer

Task:

crystals of a substance changed their color on heating in a closed vessel but regained after sometimes, when they allowed to cool down. name the substance

Answer:

Crystal hydrates – salts that contain coordinated molecules of water. When they are heated, they lose water molecules. But if the vessel is closed, water remains in the vessel (in the form of the gas). When the system is cooled, the water becomes liquid and is coordinated to the metal once more. Water molecules coordinated to the metal define the color of the substance. For example, CuSO45H2O(blue)CuSO4(s)(white)+H2O(g)\mathrm{CuSO_4 \cdot 5H_2O(blue)} \leftrightarrow \mathrm{CuSO_4(s)(white)} + \mathrm{H_2O(g)}

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