
So, products of reaction 2NaOH+CO2→Na2CO3+H2O is mixture or solution of Na2CO3+H2O , so it is not pure substance.
Products of reaction NaOH+HCl→NaCl+H2O is mixture or solution of NaCl+H2O , so it is not pure substance.
Products of reaction 2KI+Pb(NO3)2→2KNO3+PbI2 is not mixture of KNO3 and PbI2 , because PbI2 is precipitate and it is pure substance.
Products of reaction CaCO3→CaO+CO2 is not mixture, because CaO is solid and CO2 gas, so there are two pure substances as products.