Question #21833

the hydrogen ion concentration of a solution prepared by diluting 50. mL of 0.10 M HNO3(aq) with water to 500. mL of solution is?

Expert's answer

The hydrogen ion concentration of a solution prepared by diluting 50 mL of 0.10 M HNO3(aq) with water to 500 mL of solution is?

**Solution:**

Amount of substance of HNO3HNO_{3} in 50 mL of 0.10 M HNO3(aq)HNO_{3}(aq) is:


ν(HNO3)=(50 mL)×(0.1molL)=0.05 L×0.1molL=0.005 mol=5×103 mol\nu(HNO_{3}) = (50 \text{ mL}) \times \left(0.1 \frac{\text{mol}}{\text{L}}\right) = 0.05 \text{ L} \times 0.1 \frac{\text{mol}}{\text{L}} = 0.005 \text{ mol} = 5 \times 10^{-3} \text{ mol}


As HNO3 is a strong electrolyte (fully ionized):


HNO3+NO3HNO_{3} \rightarrow +NO_{3}^{-}


Thus:


ν(HNO3)=ν(H+)\nu(HNO_{3}) = \nu(H^{+})


So:


M(H+)=ν(H+)500 mL=5×103 mol0.5 L=0.01 MM(H^{+}) = \frac{\nu(H^{+})}{500 \text{ mL}} = \frac{5 \times 10^{-3} \text{ mol}}{0.5 \text{ L}} = 0.01 \text{ M}


**Answer:** hydrogen ion concentration is 0.01 M

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