Calculate each of the following quantities for an ideal gas: a) The volume of the gas in litre, if 2.57 moles have a pressure of 1.86 atm at a temperature of -12ºC. b) The absolute temperature of a gas at which 6.79 X 10 2 moles occupies 164 ml at 893 torr. c) The pressure in atm , if 8.25 X 10 2 moles occupies 255 mL at 15°C. d) If oxygen gas is used, calculate the mass of the oxygen gas in grams, if 5.49 L at 45ºC has a pressure of 11.25 kPa.
a) No of moles(n) = 2.57 mol
Pressure of gas(P) = 1.86 atm
Temperature(T) = - 12C = 261K
Gas Constant(R) = 0.0821 L.atm/mol.K
By Ideal Gas Law, PV = nRT
So, V = nRT/P =
2.57 × 0.0821 × 261 / 1.86 = 29.607 L
So, The volume of gas = 29.607 L .
b) Volume of gas (V) = 164mL = 0.164 L
No of moles (n) = 6.79 × 10-2 mol = 0.0679 mol
Pressure of gas (P) = 893 torr
Gas Constant(R)= 62.36 L.Torr/mol.K
By Ideal Gas law, PV = nRT
So, T = PV/nR =
893 × 0.164 / 0.0679 × 62.36
So, the Temperature of gas(T) = 34.587 K
c) No of moles (n) =
8.25 × 10-2 mol = 0.0825 mol
Volume of gas (V) = 255mL = 0.255L
Temperature (T) = 15C = 288 K
Gas Constant(R) = 0.0821L.atm/mol.K
By ideal gas Law, PV = nRT
So, P = nRT/V =
0.0825 × 0.0821 × 288 / 0.255
So, the pressure of gas = 7.649 atm
d) Volume of Oxygen gas (V) = 5.49L
Temperature(T) = 45C = 318 K
Pressure of gas (P)= 11.25 kPa
Gas Constant (R) = 8.314 L.kPa/mol.K
By Ideal gas law, PV=nRT
So, n= PV/RT =
11.25 × 5.49/ 8.314 × 318
So, n = 0.023 mol
Molar mass of Oxygen gas = 32 g/mol
The mass of oxygen gas = 0.023 × 32 = 0.736 g .
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