a) 200.0 g of Ca(C2H3O2)2 was found in the chemistry laboratory.
Calculate
i. the molecular mass of 1 mole Ca(C2H3O2) 2.
ii. the number of moles of Ca(C2H3O2)2 that exists
iii. the number of Ca(C2H3O2)2 molecules present
iv. the volume at STP if Ca(C2H3O2)2 is converted to gas.
v. the molarity of a solution made by dissolving 200.0 g of
Ca(C2H3O2)2 in 200 ml of water
Solution:
Ca(C2H3O2)2 - calcium acetate
m[Ca(C2H3O2)2] = 200.0 g
(i):
Molecular mass calculation:
M[Ca(C2H3O2)2] = 40.078 + (12.0107 × 2 + 1.00794 × 3 + 15.9994 × 2) × 2 = 158.166 g mol-1
The molecular mass of 1 mole Ca(C2H3O2)2 is 158.166 g mol-1.
(ii):
One mol of Ca(C2H3O2)2 has a mass of 158.166 grams.
Thus 200 grams of Ca(C2H3O2)2 is:
(200 g Ca(C2H3O2)2) × (1 mol Ca(C2H3O2)2 / 158.166 g Ca(C2H3O2)2) = 1.2645 mol Ca(C2H3O2)2
1.2645 mol of Ca(C2H3O2)2 has a mass of 200.0 grams.
(iii):
One mole of any substance contains 6.022×1023 atoms/molecules.
Hence,
Number molecules = (1.2645 mol) × (6.022×1023 molecules / 1 mol) = 7.615×1023 molecules
Number molecules of Ca(C2H3O2)2 is 7.615×1023 molecules.
(iv):
At STP, one mole of any gas occupies a volume of 22.4 L.
Thus 1.2645 mol of Ca(C2H3O2)2 occupies:
(1.2645 mol × 22.4 L) / 1 mol = 28.325 L of Ca(C2H3O2)2
1.2645 mol of Ca(C2H3O2)2 occupies a volume equal to 28.325 L.
(v):
Molarity of Ca(C2H3O2)2 = Moles of Ca(C2H3O2)2 / Solution volume
1.2645 mol of Ca(C2H3O2)2 has a mass of 200.0 grams (according to the (ii) calculation).
Solution volume = 200 mL = 0.2L
Hence,
Molarity of Ca(C2H3O2)2 = 1.2645 mol / 0.2 L = 6.3225 mol/L = 6.3225 M
The molarity of a solution is 6.3225 M.
Answer:
(i): M[Ca(C2H3O2)2] = 158.166 g mol-1;
(ii): n[Ca(C2H3O2)2] = 1.2645 mol;
(iii): N[Ca(C2H3O2)2] = 7.615×1023 molecules;
(iv): V[Ca(C2H3O2)2] = 28.325 L;
(v): CM[Ca(C2H3O2)2] = 6.3225 M.
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