The simplest method is to add silver nitrate solution to samples solutions:
I−+AgNO3=>AgI+NO3−I^-+AgNO_3 =>AgI + NO_3^-I−+AgNO3=>AgI+NO3− AgI is a yellow precipitate
Br−+AgNO3=>AgBr+NO3−Br^-+AgNO_3 =>AgBr + NO_3^-Br−+AgNO3=>AgBr+NO3− AgBr is a yellowish precipitate
Cl−+AgNO3=>AgCl+NO3−Cl^-+AgNO_3 =>AgCl + NO_3^-Cl−+AgNO3=>AgCl+NO3− AgCl is a white precipitate
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