The percentage of CH3OH by volume is defined as:
ϕMeOH=VMeOH+VH2OVMeOH∗100%;
We have to modify this equation:
VMeOH∗ϕMeOH+ϕMeOH∗VH2O=100%∗VMeOH;
VMeOH(100%−ϕMeOH)=ϕMeOH∗VH2O;
VMeOH=100%−ϕMeOHϕMeOH∗VH2O=100%−80%80%∗200mL=800mL.
Thus, 800 mL of pure methyl alcohol should be added to 200 mL of water.
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