"2MnO_2 + 2KOH + O_2 = 2 KMnO_4 + H_2"
We know KMnO4 is a strong oxidizing agent.So it will oxidise H2 andreduce itself to form MnO2 and KOH.
The backward reaction is more favourable,so,oxygen is produced.Thus,there is excess oxygen gas.
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