Question #97088
Suppose that 2 mol of gas is measured at 2 atm pressure to have a volume of 5 L, a temperature of 300 K. If the conditions change such that there are 4 mol at 4 atm and at 270 K, what is the new volume?
1
Expert's answer
2019-10-23T07:00:54-0400

Q97088


Solution:

Given:


Initial conditions;

ni=2moln_i=2 mol ---(initial no. of moles)

Pi=2atm.P_i=2 atm. ---(initial pressure)

Vi=5LV_i=5 L ---(initial volume)

Ti=300KT_i=300K ---(initial temperature of gas)


Final conditions;

nf=4moln_f=4 mol ---(final no. of moles)

Pf=4atm.P_f=4 atm. ---(final pressure)

Tf=270KT_f=270K ---(final temperature)


To find: VfV_f (final volume of the gas)


Using Ideal Gas Law; PV=nRTPV=nRT

where, R=gasconstantR=gas constant


PV/nT=constant\therefore PV/nT=constant

    PiVi/niTi=PfVf/nfTf\implies P_iV_i/n_iT_i= P_fV_f/n_fT_f


Vf=(PiVi/niTi)(nfTf/Pf)\therefore V_f=(P_iV_i/n_iT_i)*(n_fT_f/P_f)


Substituting the given values, we get;

Vf=((2atm5L)/(2mol300K))V_f=((2atm*5L)/(2 mol*300K)) (4mol270K/4atm)*(4mol*270K/4 atm)

=4.5L=4.5L (Answer)


Thus new volume of the gas is 4.5L4.5 L


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