We can write the reaction as
SO2 + 2H2S ⟶ (3/8)S8 + 2H2O
Now we can say from 1 mole SO2 and 2 moles of H2S 3/8 moles of S8 is formed.
85 gm SO2 = 85/64 mole SO2
85 gm H2S = 85/34 moles of H2S
For 85/34 moles of H2S, ( 85/34)*(1/2)*(3/8) moles of S8 is formed.
For 85/64 moles of SO2, (85/64)*(3/8) moles of S8 is formes.
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