Question #93862
What type of reaction involves the reaction of oxalate ions and permanganate ions?
1
Expert's answer
2019-09-16T03:52:31-0400

It is an example of redox reaction where oxalate ions are oxidized into CO2CO_2 and permanganate ions are reduced from Mn+7Mn^{+7} to Mn+2Mn^{+2}

The reactions are as follows(in acidic solution):

The oxidation half-reaction is:

5C2O410CO2(g)+10e5C_2O_4^-\to 10CO_2(g) + 10e^-

The reduction half-reaction is:

2MnO4+16H++10e2Mn+2(aq)2MnO_4+ 16H^+ + 10e^- \to 2Mn^{+2}(aq) +8H2O(l)+ 8H_2O(l)

In other words, the oxalate ion is oxidized by the permanganate ion (and the permanganate ion is reduced).

The overall balanced redox reaction is the combination of the two balanced half-reactions:

2MnO4+16H++5C2O4210CO2(g)+2Mn+2(aq)+8H2O(l)2MnO^{-4} + 16H^+ + 5C_2O_4^{-2} \to 10CO_2(g) + 2Mn^{+2}(aq) + 8H_2O(l)


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