Question #90330

How many milliliters of a 0.8 M solution of citric acid would be needed to react with 15 grams of baking soda?
citric acid (C6H8O7) baking soda (NaHCO3)

the equation that demonstrates reaction:
C6H8O7 + 3NaHCO3 → Na3C6H5O7 + 3H2O + 3CO2

Expert's answer

Given:

cC6H8O7=0.8M=0.8mol/Lc_{C_6H_8O_7}=0.8 M = 0.8 mol/LmNaHCO3=15gm_{NaHCO_3} = 15 g

Solution:

From the reaction equation:


3∗nC6H8O7=nNaHCO33* n_{C_6H_8O_7} = n_{NaHCO_3}


Molar mass of baking soda is:


MNaHCO3≈23+1+12+3∗16=84g/molM_{NaHCO_3} \approx 23 + 1 + 12 + 3 * 16 = 84 g/mol

So,


nNaHCO3=mNaHCO3/MNaHCO3n_{NaHCO_3} = m_{NaHCO_3}/M_{NaHCO_3}

And:


nC6H8O7=13∗nNaHCO3n_{C_6H_8O_7} = \frac{1}{3}*n_{NaHCO_3}

From definition of molarity:


VC6H8O7=nC6H8O7cC6H8O7=nNaHCO33∗cC6H8O7=mNaHCO3/MNaHCO33∗cC6H8O7V_{C_6H_8O_7} = \frac{n_{C_6H_8O_7}}{c_{C_6H_8O_7}} = \frac{n_{NaHCO_3}}{3* c_{C_6H_8O_7}} = \frac{m_{NaHCO_3}/M_{NaHCO_3} }{3* c_{C_6H_8O_7}}

Calculating:


VC6H8O7=15/843∗0.8=584∗0.8≈0.0744L=74.4mLV_{C_6H_8O_7} = \frac{15/84 }{3* 0.8}= \frac{5}{84* 0.8} \approx 0.0744 L = 74.4 mL

Answer: 74.4 mL


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