We will use this formula to count out the pH of the buffer solution.
pH = pKa + lg(c(C3H5NaO3) * V(C3H5NaO3) / c(C3H6O3) * V(C3H6O3)) = 3.86 + lg(0.234 mol/L * 0.07 L / 0.123 mol/L * 0.03 L) = 3.86 + lg(0.01701/0.00396) = 3.86 + lg4.295 = 3.86 + 0.633 = 4.493.
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