In 100g of air:
"n(O2)=\\dfrac{21g}{32g\/mol}=0.66 moles"
"n(N2)=\\dfrac{79g}{28g\/mol}=2.82moles"
"0.66moles+2.82moles=3.48 moles"
"V=\\dfrac{nRT}{P}=\\dfrac{3.48*0.0821*273K}{1atm}=78L"
"density=\\dfrac{m}{V}=\\dfrac{100g}{78L}=1.282g\/L=1.282kg\/m^{3}"
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