Answer to Question #87335 in General Chemistry for solo

Question #87335
1) phosphorus pentachloride is produced by the reaction between phosphine and chlorine gas. What mass of chlorine gas would be required to produce 0.015kg of phosphorus pentachloride
1
Expert's answer
2019-04-02T05:58:36-0400

The balanced equation for considered reaction can be written as follows

PH3(g)+4Cl2(g)PCl5(g)+3HCl(l)PH_3 (g) + 4 Cl_2 (g) \rightarrow PCl_5 (g) + 3 HCl (l)

m(Cl2)M(Cl2)n(Cl2)=m(PCl5)M(PCl5)n(PCl5)\frac{m(Cl_2)}{M(Cl_2) \cdot n(Cl_2)} = \frac{m(PCl_5)}{M(PCl_5) \cdot n(PCl_5)}

m(Cl2)=m(PCl5)M(Cl2)n(Cl2)M(PCl5)n(PCl5)m(Cl_2) = \frac{m(PCl_5) \cdot M(Cl_2) \cdot n(Cl_2)}{M(PCl_5) \cdot n(PCl_5)}

M(Cl2)=235.453=70.906  g/molM(Cl_2) = 2 \cdot 35.453 = 70.906 \; g/mol

M(PCl5)=130.974+535.453=208.239  g/molM(PCl_5) = 1 \cdot 30.974 + 5 \cdot 35.453 = 208.239 \; g/mol

m(Cl2)=0.01570.9064208.23910.0204  kg=20.4  gm(Cl_2) = \frac{0.015 \cdot 70.906 \cdot 4}{208.239 \cdot 1} \approx 0.0204 \; kg = 20.4 \; g


Answer: 20.4 g.


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