Answer:
a) 1.350 M = 1.350 moles (NH4)2HPO4/L solution.
1.350 moles (NH4)2HPO4 = 1.350*(132.0562 g/mole) = 178.27 g
mass of 1000 ml of the solution is 1000*1.045 g/ml = 1045 g and 178.27 g is (NH4)2HPO4 therefore
w = mass of solute/mass of solution
w = (178.27/1045) * 100 = 17 %
b) 1.350 mole - 1000 ml
x mole - 2.55 ml
x = 0.003 mole (NH4)2HPO4
1 mole (NH4)2HPO4 - 9 mole of H
0.003 mole - x mole of H
x = 0.027 mole of H
N = Na*n, where Na is Avogadro constant, n is the amount of substance
N = 6.02*10^23 * 0.027 = 1.62*10^22
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