Question #81895

Methanol (CH3OH) is produced commercially by the catalyzed reaction of carbon monoxide and hydrogen:
CO(g)+2H2(g)⇌CH3OH(g).
An equilibrium mixture in a 2.50 L vessel is found to contain 0.0243 mol CH3OH, 0.160 mol CO, and 0.301 mol H2 at 500 K.
Calculate Kc at this temperature.
1

Expert's answer

2018-10-11T08:13:09-0400

Question #81895, Chemistry / General Chemistry | for completion

Methanol (CH3OH) is produced commercially by the catalyzed reaction of carbon monoxide and hydrogen:

CO(g)+2H2(g)CH3OH(g)\mathrm{CO(g) + 2H2(g)\rightleftharpoons CH3OH(g)}

An equilibrium mixture in a 2.50 L vessel is found to contain 0.0243 mol CH3OH, 0.160 mol CO, and 0.301 mol H2 at 500 K.

Calculate Kc at this temperature.

Answer:

CCH3OH=0.0243mol/2.5L=0.00972M\mathrm{C_{CH3OH} = 0.0243 mol / 2.5 L = 0.00972 M}

CCO=0.16mol/2.5L=0.064M\mathrm{C_{CO} = 0.16 mol / 2.5 L = 0.064 M}

CH2=0.301mol/2.5L=0.1204M\mathrm{C_{H2} = 0.301 mol / 2.5 L = 0.1204 M}

Formula: KC=CCH3OH/CCO×(CH2)2K_{C} = C_{CH3OH} / C_{CO} \times (C_{H2})^{2}

KC=0.00972/0.064×(0.1204)2=10.48K_{C} = 0.00972 / 0.064 \times (0.1204)^{2} = 10.48

KC=10.48K_{C} = 10.48

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