Question #74792

In a titration experiment, 13.3 mL of an aqueous H2SO4 solution was titrated with 0.6 M NaOH solution. The equivalence point in the titration was reached when 13.8 mL of the NaOH solution was added. What is the molarity of the H2SO4 solution?

Expert's answer

Answer on Question #74792, Chemistry / General Chemistry

In a titration experiment, 13.3 mL of an aqueous H₂SO₄ solution was titrated with 0.6 M NaOH solution. The equivalence point in the titration was reached when 13.8 mL of the NaOH solution was added. What is the molarity of the H₂SO₄ solution.

Solution:

2NaOH+H2SO4Na2SO4+2H2O2 \mathrm{NaOH} + \mathrm{H_2SO_4} \rightleftharpoons \mathrm{Na_2SO_4} + 2 \mathrm{H_2O}mols(NaOH)=M×Vmols \left(NaOH\right) = M \times Vmols(NaOH)=0.6M1L×0.0138L=0.00828molmols \left(NaOH\right) = \frac{0.6 M}{1 L} \times 0.0138 L = 0.00828 mol


Look at the coefficients in the balanced equation


mols(H2SO4)=12×mols(NaOH)mols \left(H_2SO_4\right) = \frac{1}{2} \times mols \left(NaOH\right)mols(H2SO4)=12×0.00414molmols \left(H_2SO_4\right) = \frac{1}{2} \times 0.00414 molM(H2SO4)=mols(H2SO4)V(H2SO4)M \left(H_2SO_4\right) = \frac{mols \left(H_2SO_4\right)}{V \left(H_2SO_4\right)}M(H2SO4)=0.00414mol0.0133L=0.3MM \left(H_2SO_4\right) = \frac{0.00414 mol}{0.0133 L} = 0.3 M


Answer: 0.3 M (H₂SO₄)


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